One does not bleed the lines by opening the vent on the baseboard unit.
Flushing the system or zone to remove air generally has to be done at the boiler.
The process and steps involved vary with the boiler manufacturer so you’d have to contact the Mfg or a local supplier for steps on how to flush the line.
It’s possible to have a faulty vent on the main line of the zone at the boiler that may need to be replaced.
Might be best to simply call a pro.